Arsenolite

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Arsenolite

Arsenolite-333170.jpg
Arsenolite from the White Caps Mine, Manhattan District, Nye County, Nevada (size: 6.0 x 4.3 x 2.9 cm)

General
Category
Oxide mineral

Formula
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(repeating unit)

As4O6
Strunz classification
4.CB.50
Crystal system
Cubic
Crystal class
Hexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space group
Fd3m
Unit cell
a = 11.074 Å; Z = 16
Identification
Formula mass
197.841 g/mol
Color
White, pale blue, pink to pale yellow if impure
Crystal habit
Common as tiny octahedra; aggregates or crusts; botryoidal, stalactitic
Cleavage
On 111
Fracture
Conchoidal

Mohs scale
hardness

1.5
Luster
Vitreous to silky; may be earthy or dull
Streak
white /pale white
Diaphaneity
Transparent
Specific gravity
3.87
Optical properties
Isotropic; may be anomalously anisotropic
Refractive index
n = 1.755
Other characteristics
Astringent, sweetish taste; toxic
References
[1][2][3]

Arsenolite is an arsenic mineral, chemical formula As4O6. It is formed as an oxidation product of arsenic sulfides. Commonly found as small octahedra it is white, but impurities of realgar or orpiment may give it a pink or yellow hue. It can be associated with its dimorph claudetite (a monoclinic form of As2O3) as well as realgar (As4S4), orpiment (As2S3) and erythrite, Co3(AsO4)2·8H2O.[1]


Arsenolite belongs to the minerals which are highly toxic.[3]



Occurrence


It was first described in 1854 for an occurrence in the St Andreasberg District, Harz Mountains, Lower Saxony, Germany.[3]


It occurs by the oxidation of arsenic-bearing sulfides in hydrothermal veins. It also occurs as a result of mine or coal seam fires.[1]



References




  1. ^ abc Handbook of Mineralogy


  2. ^ Webmineral


  3. ^ abc Mindat



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